Entrance Exam Semmelweis 2024/2025 Questions with Complete Solutions Electron configuration for cations - Correct Answer Subtract 1 from exponent of highest n-value orbital (ex. remove from 4s before 3d) Ag+ = [Kr]5s^1 4d^9 Electron configuration for anions - Correct Answer Add 1 to closest orbital Cl- = [Ne]3s^2 3p^6 Atomic orbitals - Correct Answer s, p, d, f Primary vs secondary structures of proteins - Correct Answer Primary - AA chain (linked by peptide bonds) Secondary - stabilized by non-covalent bonds (alpha helices & beta sheets) Most bonds in organic compounds are - Correct Answer covalent Properties of water - Correct Answer 1. polar
- capable of adhesion and cohesion
- high heat capacity (so it's hard to raise its temp)
- great solvent
- high heat of vaporization (allows humans to cool off via sweat)
- water is less dense as a solid than a liquid
Intermolecular forces of water - Correct Answer hydrogen bonding 1 / 3
Solution components - Correct Answer 1. solvent (product being dissolved)
- solute (medium for dissolving solvent)
- alkali metals (group 1) & NH4+ cations
- NO3- or CH3COO- anions
- Cl, Br, I (except when bonded to Ag+, Pb2+ or Hg2+)
- sulfate ions (except when with Ca2+, Sr2+, Ba2+, Pb2+)
Molarity - Correct Answer the number of moles of solute per liter of solution Solubility rules - Correct Answer SOLUBLE
INSOLUBLE
- Metal oxides (except CaO, SrO, BaO)
- Hydroxides (except when with Ca2+, Sr2+, Ba2+)
- Carbonates, phosphates, sulfides, and sulfites (unless bound to alkali metal or NH4+)
- Ksp = x^2
- Ksp = 4x^3
- Ksp = 27x^4 2 / 3
Solubility product - Correct Answer Ksp = [A]^a[B]^b **only products because we don't include solids in the equilibrium expression for NaCl
for PbCl2
for Cr(OH)3
Large Ksp means - Correct Answer strong electrolyte (more soluble) Strong acids - Correct Answer So I brought no clean clothes
1. H2SO4
2. HI
- HBr
4. HNO3
- HCl
- HClO4
- HClO3
- LiOH
Strong bases - Correct Answer 1. NaOH
3. KOH
- CsOH
- RbOH
- Ba(OH)2
- Ca(OH)2
- Sr(OH)2
- / 3
Bases can certainly look pleasing (K), really something strong (Na) Le Chatlier's principle: pressure - Correct Answer pressure applied (or volume reduced) --> equilibrium proceeds in direction with fewer moles pressure removed (or volume increased) --> equilibrium proceeds in direction with more moles Le Chatlier's principle: temperature - Correct Answer increasing temperature