How many electrons are unpaired in the orbitals of nitrogen?

The correct answer and explanation is:

The correct answer is: 3 unpaired electrons


Explanation:

To determine the number of unpaired electrons in nitrogen, we must examine its electron configuration and orbital diagram.

Step 1: Atomic Number of Nitrogen

Nitrogen has an atomic number of 7, which means it has 7 electrons in a neutral atom.

Step 2: Electron Configuration

The electron configuration of nitrogen is:
1s² 2s² 2p³

This means:

  • Two electrons fill the 1s orbital.
  • Two electrons fill the 2s orbital.
  • Three electrons occupy the 2p orbitals.

Step 3: Filling the 2p Orbitals

The 2p subshell has three orbitals: 2px, 2py, and 2pz. According to Hund’s Rule, electrons will fill these orbitals singly before pairing up.

So, the 2p electrons are distributed as:

  • 1 electron in 2px
  • 1 electron in 2py
  • 1 electron in 2pz

Each of these orbitals contains 1 unpaired electron, resulting in three unpaired electrons.

Orbital Diagram:

1s:  ↑↓  
2s:  ↑↓  
2p:  ↑  ↑  ↑  
     px py pz

Each arrow represents an electron. Since the 2p orbitals each have a single electron with parallel spins, all three are unpaired.

Conclusion:

Nitrogen has 3 unpaired electrons in its ground-state electron configuration. This configuration explains several chemical properties of nitrogen, including its paramagnetism (attraction to a magnetic field) and its ability to form three covalent bonds, as seen in molecules like ammonia (NH₃).

Understanding the number of unpaired electrons is essential in predicting the magnetic behavior, reactivity, and bonding characteristics of an atom in chemistry.

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